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Creating Optical Activity: Total Spontaneous Resolution and Viedma Ripening


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Title: Creating Optical Activity: Total Spontaneous Resolution and Viedma Ripening
Authors: Björemark, Per Martin
E-mail: per.martin.bjoremark@gu.se
Issue Date: 18-Oct-2017
University: University of Gothenburg. Faculty of Science
Institution: Department of Chemistry and Molecular Biology ; Institutionen för kemi och molekylärbiologi
Parts of work: I. Theonitsa Kokoli, Per Martin Björemark and Mikael Håkansson. Copper (I) halide complexes with prochiral sulfide ligands; Manuscript

II. Theonitsa Kokoli, Susanne Olsson, Per Martin Björemark, Staffan Persson and Mikael Håkansson. Toward absolute asymmetric synthesis of coordination polymers with bidentate sulfide ligands. Journal of Organometallic Chemistry, 2013 (724), 17-22.
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III. Theonitsa Kokoli, Susanne Olsson, Per Martin Björemark, Jonas Sundberg, Anders Lennartsson, Christine J. McKenzie and Mikael Håkansson. Absolute asymmetric synthesis: Protected substrate oxidation. Chemistry-a European Journal, 2015 (21), 13, 5211-5219.
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IV. Per Martin Björemark, Susanne Olsson, Theonitsa Kokoli, Mikael Håkansson. Absolute Asymmetric Synthesis of a Tetrahedral Silver Complex. Chemistry-a European Journal, 2015 (21), 24, 8750-8753.
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V. Per Martin Björemark, Johan Jönsson and Mikael Håkansson. Absolute Asymmetric Synthesis: Viedma Ripening of Co(bpy)3(2+) and Solvent-Free Oxidation to Co(bpy)3(3+). Chemistry-a European Journal, 2015 (21), 30 10630-10633.
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VI. Per Martin Björemark and Mikael Håkansson. Viedma Ripening of Group VI Metal Carbonyl Complexes. Manuscript.

VII. Per Martin Björemark, Jonas Sundberg, Vibe B. Jacobsen, Christine J. McKenzie, and Mikael Håkansson. Grinding Achiral Crystals to Enantiopurity. Manuscript
Date of Defence: 2017-11-10
Disputation: Kl. 10.00 Sal SB-H1, Sven Hultins Gata 6, Johanneberg.
Degree: Doctor of Philosophy
Publication type: Doctoral thesis
Keywords: Optical activity
absolute asymmetric synthesis
total spontaneous resolution
Viedma ripening
grinding
chirality
conglomerate
coordination compound
coordination polymer
single crystal X-ray diffraction
solvent free oxidation
nantioselective sulfide oxidation
solid state VCD
Abstract: The creation of optical activity has been considered as something impossible even though reports of such creation via total spontaneous resolution since the 1940´s have been published. More recently Viedma ripening have been developed that also produce enantiopure bulk product. Both methods are examples of absolute asymmetric synthesis i.e. the synthesis of optically active product from non-optically active starting materials, catalysts or auxiliaries. In this work twenty-four new compounds hav... more
ISBN: 978-91-629-0327-5
URI: http://hdl.handle.net/2077/53817
Appears in Collections:Doctoral Theses from University of Gothenburg / Doktorsavhandlingar från Göteborgs universitet
Doctoral Theses / Doktorsavhandlingar Institutionen för kemi och molekylärbiologi

 

 

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