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MECHANISTIC INVESTIGATIONS OF TRANSITION METAL CATALYZED REACTIONS


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Title: MECHANISTIC INVESTIGATIONS OF TRANSITION METAL CATALYZED REACTIONS
Authors: Kleimark, Jonatan
E-mail: jonatan.kleimark@chem.gu.se
Issue Date: 14-Dec-2011
University: University of Gothenburg. Faculty of Science
Institution: Department of Chemistry ; Institutionen för kemi
Parts of work: Palladium-Catalyzed Allylic Sulfinylation and the Mislow–Braverman–Evans Rearrangement CHEMISTRY - A EUROPEAN JOURNAL Volume 17, Issue 50, December 9, 2011, Pages: 13963–13965, Jonatan Kleimark, Dr. Guillaume Prestat, Prof. Giovanni Poli and Prof. Per-Ola Norrby Article first published online : 17 NOV 2011,
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Sterically Governed Selectivity in Palladium-Assisted Allylic Alkylation Jonatan Kleimark, Charlotte Johansson, Susanne Olsson, Mikael Hakansson, Sverker Hansson, Bjorn Åkermark, and Per-Ola Norrby Organometallics, 2011, 30 (2), pp 230–238 Publication Date (Web): December 23, 2010 (Article)
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Mechanistic Investigation of Iron-Catalyzed Coupling Reactions CHEMCATCHEM Volume 1, Issue 1, August 24, 2009, Pages: 152–161, Jonatan Kleimark, Anna Hedström, Per-Fredrik Larsson, Charlotte Johansson and Per-Ola Norrby Article first published online : 16 JUN 2009,
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Transmetalation versus β-Hydride Elimination: The Role of 1,4-Benzoquinone in Chelation-Controlled Arylations using Arylboronic Acids C. Sköld, J. Kleimark, A. Trejos, L. R. Odell, S. O. Nilsson Lill, P.-O. Norrby, M. Larhed Accepted for publication in Chemistry – a European Journal

Mild and Efficient Nickel-Catalyzed Heck Reactions with Electron Rich Olefins T. Gøgsig, J. Kleimark, S. O. Nilsson Lill, S. Korsager, A. Lindhart, P.-O. Norrby, T. Skrydstrup Accepted for publication in Journal of the American Chemical Society

Low Temperature Studies of Iron Catalyzed Cross Coupling of Alkyl Grignards with Aryl Electrophiles J. Kleimark, P.-F. Larsson, P. Emamy, A. Hedström, P.-O. Norrby Accepted for publication in Advanced Synthesis and Catalysis
Date of Defence: 2012-01-20
Disputation: Fredagen den 20 januari 2012, kl 09.15, sal KC, Kemigården 4, Chalmersområdet
Degree: Doctor of Philosophy
Publication type: Doctoral thesis
Keywords: alkene insertion
allylic alkylation
catalysis
cross coupling
density funtional theory
free energy surface
iron
kinetic investigation
Mizoroki-Heck reaction
nickel
palladium
reaction mechanism
sulfinylation
transition metal
Abstract: Transition metal catalyzed reactions have had a large impact on the human progress for the last century. Several extremely important areas, such as the agricultural industry and the plastic industry, have benefited from this development. The evolution of different transition metal catalysts has also been very important for the pharmaceutical industry. One vital factor when developing new and more effective catalysts is to obtain mechanistic insights. In this thesis, several different methods to ... more
ISBN: 978-91-628-8394-2
URI: http://hdl.handle.net/2077/27967
Appears in Collections:Doctoral Theses / Doktorsavhandlingar Institutionen för kemi
Doctoral Theses from University of Gothenburg / Doktorsavhandlingar från Göteborgs universitet

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