Experimental studies of cluster ions containing water, ammonia, pyridine and bisulphate
Molecular cluster ions are fascinating subjects of study. Bridging the size gap between molecules and bulk, they often display non-trivial size dependent behaviour and properties. As an example, for some cluster types there are certain sizes that are found in unusually high abundance in a produced cluster distribution, these are referred to as gmagic numbers h. Apart from being interesting in their own right and serving as useful model systems in a number of applications, molecular clusters have a very real and important role in the vast and dynamic system we refer to as the atmosphere. Molecular clusters act as precursors for the formation of atmospheric particles. As such, it is necessary to learn as much as possible about the formation, growth, physical properties and chemistry of these clusters, because the particles they form will ultimately have a large effect on the global climate. This work investigates the properties of some ionic molecular clusters and their gas phase reactions with heavy water and ammonia, and also the effects of collision induced dissociation on air. This is done in cluster beam experiments, using two different experimental setups. The first instrument is a quadrupole-time-of-flight instrument, consisting of an electrospray ion source, a quadrupole mass filter, a collision cell and a time-of-flight mass spectrometer. In this instrument, relative reaction cross sections were measured for H+(H2O)n, H+(NH3)1(H2O)n and H+(pyridine)1.3(H2O)n colliding with D2O; and for H+(H2O)n, H+(pyridine)1.2(H2O)n and H+(NH3)1(pyridine)1(H2O)n colliding with NH3. The results for the reaction H+(pyridine)1(H2O)n + NH3 were used to improve a kinetic model of the atmospheric positive ion composition. Abundance spectra and evaporation patterns were recorded for all clusters. It was found that protonated clusters containing water and pyridine do not have magic numbers in the investigated size range (. 1500 u), unlike clusters consisting of water, pyridine and ammonia. Furthermore the magic numbers of H+(NH3)1(pyridine)1(H2O)n were the same as those recorded for H+(NH3)1(H2O)n. Cluster reactions with D2O proceed through a short-lived reaction complex. The clusters add the heavy water molecule and subsequently lose a D2O, HDO or H2O molecule; the latter two reaction channels are associated with a cluster mass increase of one or two atomic mass units, respectively. The formation of a HDO species in a cluster requires proton mobility, and is known to occur in H+(H2O)n clusters. The reaction channel leading to formation of HDO was not observed for protonated water clusters containing an ammonia or pyridine molecule, which is attributed to the proton being bound in place by the Bronsted base. However, the experiments indicate proton mobility in clusters with two or three pyridine molecules, H+(pyridine)2.3(H2O)n. Quantum chemical calculations suggest that this may be due to transfer of the proton to a water molecule, forming H3O+, or due to proton transfer between the two pyridine molecules along a wire of hydrogen bonds. The second instrument is a double sector instrument, having a magnetic sector, a collision cell and an electrostatic sector. Collision induced dissociation of H+(NH3)m(H2O)n clusters (m = 4.6) indicate that clusters having six NH3 prefer to lose NH3, while clusters with four or five NH3 prefer to lose H2O.
Parts of work
Paper I Isotope exchange and structural rearrangements in reactions between sizeselected ionic water clusters, H3O+(H2O)n and NH4+(H2O)n, and D2O Patrik U. Andersson, Mauritz J. Ryding, Osamu Sekiguchi and Einar Uggerud Physical Chemistry Chemical Physics, 2008. 10(40): p. 6127-6134.::doi::10.1039/B804584DPaper II Isotope exchange in reactions between size-selected ionic water clusters, H+(pyridine)m(H2O)n, and D2O Mauritz J. Ryding, Alexey S. Zatula, Patrik U. Andersson and Einar Uggerud Physical Chemistry Chemical Physics, 2011. 13(4): p. 1356-1367.::doi::10.1039/C0CP00416BPaper III Proton mobility and stability of water clusters containing the bisulfate anion, HSO4−(H2O)n Alexey S. Zatula, Patrik U. Andersson, Mauritz J. Ryding and Einar Uggerud Physical Chemistry Chemical Physics, 2011. 13(29): p. 13287-13294.::doi::10.1039/C1CP21070JPaper IV Reactions of H+(pyridine)m(H2O)n and H+(NH3)1(pyridine)1(H2O)n with NH3: experiments and kinetic modelling under tropospheric conditions Mauritz J. Ryding, Åsa M. Jonsson, Alexey S. Zatula, Patrik U. Andersson and Einar Uggerud Atmospheric Chemistry and Physics Discussions, 2011. 11(9): p. 24535–24566.::doi::10.5194/acpd-11-24535-2011Paper V Structural rearrangements and magic numbers in reactions between pyridine containing water clusters and ammonia Mauritz J. Ryding, Patrik U. Andersson, Alexey S. Zatula and Einar Uggerud Manuscript in preparationPaper VI Stability and Structure of Protonated Clusters of Ammonia and Water, H+(NH3)m(H2O)n Preben Hvelplund, Theo Kurtén, Kristian Støchkel, Mauritz J. Ryding, Steen Brøndsted Nielsen and Einar Uggerud Journal of Physical Chemistry A, 2010. 114(27): p. 7301-7310.::doi::10.1021/jp104162k
Doctor of Philosophy
University of Gothenburg. Faculty of Science
Department of Chemistry ; Institutionen för kemi
Fredagen den 28 oktober 2011, kl. 10.15, seminarierum 10-an, kemihuset, kemigården 4.
Date of defence
collision induced dissociation (CID)
electrospray ionization (ESI)